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Evidence for specific base catalysis in N-dealkylation reactions catalyzed by cytochrome P450 and chloroperoxidase. Differences in rates of deprotonation of aminium radicals as an explanation for high kinetic hydrogen isotope effects observed with peroxidases.

Okazaki O, Guengerich FP
J Biol Chem. 1993 268 (3): 1546-52

PMID: 8380572

MeSH Terms (16)

Alkylation Aniline Compounds Animals Catalysis Chloride Peroxidase Cytochrome P-450 Enzyme System Deuterium Free Radicals Hemoglobins Horseradish Peroxidase Kinetics Microsomes, Liver Prostaglandin-Endoperoxide Synthases Protons Rabbits Rats

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