Immobilization of Ag(i) into a metal-organic framework with -SO3H sites for highly selective olefin-paraffin separation at room temperature.

Chang G, Huang M, Su Y, Xing H, Su B, Zhang Z, Yang Q, Yang Y, Ren Q, Bao Z, Chen B
Chem Commun (Camb). 2015 51 (14): 2859-62

PMID: 25581083 · DOI:10.1039/c4cc09679g

Introduction of Ag(i) ions into a sulfonic acid functionalized MOF ((Cr)-MIL-101-SO3H) significantly enhances its interactions with olefin double bonds, leading to its much higher selectivities for the separation of C2H4-C2H6 and C3H6-C3H8 at room temperature over the original (Cr)-MIL-101-SO3H and other adsorbents at room temperature.

MeSH Terms (8)

Adsorption Alkenes Models, Molecular Molecular Conformation Organometallic Compounds Paraffin Silver Temperature

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