Nabil Saleh
Research Assistant II
Last active: 3/15/2017

A novel route to organonitrites by Pd-catalyzed cross-coupling of sodium nitrite and potassium organotrifluoroborates.

Al-Masum M, Saleh N, Islam T
Tetrahedron Lett. 2013 54 (9): 1141-1144

PMID: 24926109 · PMCID: PMC4051233 · DOI:10.1016/j.tetlet.2012.12.047

Microwave irradiated palladium-catalyzed cross-coupling reaction of potassium styryltrifluoroborates and sodium nitrite gives the corresponding styryl nitrites in high yields. Potassium aryltrifluoroborates also furnish aryl nitrites under same reaction condition. This unprecedented cross-coupling is an interesting development and has the potential to lead to new nitration protocols.

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